Magnetization Reversal Research Articles

Surface Spin Polarization in the Magnetic Response of GeTe Rashba Ferroelectric

We experimentally investigate magnetization reversal curves for a GeTe topological semimetal. In addition to the known lattice diamagnetic response, we observe narrow magnetization loop in low fields, which should not be expected for non-magnetic material. The diamagnetic hysteresis loop is unusual, so the saturation level is negative in positive fields, and the loop is passed clockwise, in contrast to standard ferromagnetic behavior. We show, that the experimental hysteresis curves can not be obtained from standard ferromagnetic ones by adding/subtracting of any linear dependence, or even by considering several interacting magnetic phases. The latter possibility is also eliminated by the remanence plots technique (Henkel or δM plots). We explain our results as a direct consequence of the correlation between ferroelectricity and spin-polarized surface states in GeTe, similarly to magnetoelectric structures.

Ries magnetic mineralogy: Exploring impact and post‐impact evolution of crater magnetism

AbstractLarge‐scale impact events are some of the most catastrophic and instantaneous geological processes in nature, and leave in their wake conspicuous geological structures with characteristic magnetic anomalies. Despite magnetic anomalies in craters being well‐documented, their relationship with the magnetic mineral composition of the target and impactites is not always straightforward. Furthermore, the influence of impact shock and post‐impact events in the magnetism of natural craters remains elusive. In the Ries crater, Germany, the negative magnetic anomalies are attributed to a reverse polarity remanent magnetization in the impact‐melt bearing lithologies. We report new chemical, rock‐, and mineral‐magnetic data from the shocked basement and impactites, from surface samples, NR73 and SUBO‐18 boreholes, and explore how temperature and hydrothermalism may influence the magnetic mineralogy in the crater. We identified shocked, pure magnetite in the basement, and low‐cation substituted magnetite in the impactites as the main magnetic carriers. The shocked basement is demagnetized but remains largely unaltered by post‐impact hydrothermalism, while the impactites show weak magnetization and are extensively altered by neutral‐to‐reducing post‐impact hydrothermalism. We suggest that the magnetic mineralogy of the demagnetized uplifted basement may contribute significantly to the magnetic anomaly variation, in line with recent findings from the Chicxulub peak‐ring.

Single or Vortex Ferroelectric and Ferromagnetic Domain Nanodot Array of Magnetoelectric BiFe0.9Co0.1O3.

Nanodots composed of multiferroic cobalt-substituted BiFeO3, a ferroelectric ferromagnet at room temperature, are fabricated by pulsed laser deposition using anodized porous alumina as masks. The obtained nanodots are approximately 60 nm in diameter, more than 10 nm in thickness, and approximately 70 Gbit/in.2 in density. Piezoresponse and magnetic force microscopies show both ferroelectricity and ferromagnetism with a single-domain nature. It is also found that the dot with 190 nm diameter had multidomain vortex ferroelectric and magnetic structures indicating the strong magnetoelectric coupling. The single-domain cobalt-substituted BiFeO3 nanodots are suitable for verifying magnetization reversal by the electric field, which is the first step in the development of low-power-consumption nonvolatile magnetic memory devices.

Macroscopic demagnetization of the sintered Nd-Fe-B magnets prepared by Tb grain boundary diffusion

Macroscopic demagnetization in sintered Nd-Fe-B magnets by Tb grain boundary diffusion (GBD) is investigated in comparison with non-GBD ones. Demagnetization curves, the coercivity distributions, Tb content, and magnetic fields of the magnets at various external fields (μ0Hext) are analyzed. As μ0Hext approaches coercivity of the GBD magnet, S-N poles form near the center, between and parallel to the original N-S poles, indicating the magnetization reversal near the center of the GBD magnet. This is distinguished from the non-GBD magnets where demagnetization occurs mainly in the pole surfaces. The mechanism for macroscopic demagnetization is discussed.

Unravelling the Highest Magnetic Anisotropy Among all the nd-Shells in [WCp2]0 Metallocene.

Single-molecule magnets (SMMs) with a large magnetization reversal barrier are predominated by the lanthanide systems due to their strong spin-orbit coupling (SOC). However, the transition metals have also emerged as potential contenders and the largest magnetic anisotropy has been identified for a cobalt system among any d-series-based SMMs (Bunting et al. Science 2018, 362, eaat7319). In this work, we have explored the magnetic anisotropy in highly axial ligand field systems of metallocene, having different d-subshell (3d4, 4d4, and 5d4). The wave function-based multireference methods including static and dynamic electron correlations have been employed to investigate the zero-field splitting (ZFS) parameters. Here, we report exceptionally large magnetic anisotropy for a 5d complex of [WCp2]0 with the highest energy barrier that is nearly twice as high as the previous record value for the Co complex. We have also observed that the axial ZFS parameter (D) is increasing down the group in the order of 3d < 4d < 5d, pertaining to a large SOC.

Chiral spin textures creation and dynamics in a rectangular nanostructure

Abstract Controlled creation of stable chiral spin textures is required to use them as an energy-efficient information carrier in spintronics. Here we have studied the stable creation of isolated chiral spin texture (skyrmion and antiskyrmion) and its pair through the magnetization reversal of a rectangular nanostructure using spin-polarized currents. An isolated spin texture is created through a negative current pulse. Dynamics of the stable spin texture are explored under external magnetic fields, and the resonant frequencies are calculated. A stable skyrmion pair is created using an asymmetric current pulse, and their interaction is studied using the Thiele equation. The stability of isolated or paired spin texture depends on the Dzyaloshinskii–Moriya interaction strength, spin-polarized current density, and pulse duration. In addition, the stability of the skyrmion pair depends on their initial separation, and a threshold for the separation between skyrmions of 78 nm is observed.

Enhanced interlayer Dzyaloshinskii–Moriya interaction and field-free switching in magnetic trilayers with orthogonal magnetization

The indirect interlayer exchange coupling (IEC) between two magnetic layers holds significant importance in the field of spintronics and has been widely used in the construction of synthetic antiferromagnets. Recently, the interlayer Dzyaloshinskii–Moriya interaction (DMI), antisymmetric counterpart of IEC, has been discovered in magnetic trilayers with a heavy-metal spacer. In this study, we present an investigation on antisymmetric and symmetric counterparts of IEC in D022-Mn3Ga/Pt/Co trilayers with orthogonal magnetization. Due to the strong interlayer DMI across the entire multilayer, the symmetry of magnetic reversal process was broken, leading to an enhanced chiral exchange-bias field of 42.7 Oe in the Co layer. In addition, field-free spin–orbit torque (SOT) switching of D022-Mn3Ga layer has been realized in Hall bar devices. In-plane field dependence analysis of the SOT switching behavior reveals that the symmetric counterpart of IEC exhibits antiferromagnetic characteristics within the spacer thickness range of 2 nm ≤ tPt ≤5 nm. Moreover, the magnitude of both antisymmetric and symmetric counterparts of IEC exhibits an exponential decreasing trend with increasing tPt. These findings hold significant implications for the design and manipulation of three-dimensional chiral spin textures in the future spintronic devices.

A universal strategy for electric field control of nonvolatile magnetization reversal

Achieving electric field control of nonvolatile magnetization reversal in van der Waals magnetic tunnel junctions (vdW MTJs) is of paramount importance for nanoscale spintronic devices with ultralow-power consumption and high-density storage. Here, a new and universal design strategy is proposed to realize nonvolatile magnetization reversal, which is based on electric field control of interlayer coupling. The nonvolatility benefits from the proposed special principle of vdW MTJ, in which the dependence of interlayer coupling energy on electric field strength follows a continuous odd function in mathematics. The feasibility of proposed strategy is proved by the MnBi2Te4/h-BN/Fe3GaTe2/h-BN/MnBi2Te4 junction. The magnetization state of Fe3GaTe2 can be reversed 180° by changing electric field directions. Moreover, the magnetization states can be preserved after removing electric field, demonstrating the nonvolatile magnetization reversal. Therefore, the present strategy provides an alternative approach to realize electric control of nonvolatile magnetization reversal in vdW MTJs for next-generation spintronic devices.

Analyzing the mechanism of reducing B content on the coercivity of sintered (Nd, Ce)-Fe-B magnets

In recent years, the research focus has shifted towards the preparation of non-heavy rare earth (RE)-Fe-B magnets with high coercivity (Hcj) by reducing the content of B element. In this work, we achieved resource-saving sintered (Nd, Ce)-Fe-B magnets by adjusting the B element content, optimizing microstructure, and enhancement of Nd/Ce element distribution. We conducted an analysis on the magnetic characteristics, phase composition, microstructure, magnetization reversal mechanism, and economic viability of these sintered magnets. With a decrease in the B element content from 0.96 wt% to 0.90 wt%, there is a increase of approximately 1 kOe in Hcj.At the same time, the temperature coefficient of Hcj has been improved, resulting in a absolute value decrease from 0.67%/°C to 0.63%/°C. The findings suggested that reducing the mass fraction of B element could facilitate the formation of a thicker grain boundary phase between the grains. It could significantly weaken the ferromagnetic coupling effect, and enhance the magnetic isolation effect between grains, resulting in a higher Hcj. From an economic perspective, compared to the cost of magnet with similar coercivity prepared by increasing the RE content, the cost of magnet with low B element content was reduced by 554.4 US$/t, approximately saving 3.08%. This study provides a new theoretical foundation and experimental basis for resource-saving sintered (Nd,Ce)-Fe-B magnet preparation.

Structure, magnetic, and electrodynamic properties of SrInxFe12‐xO4/Ni0.5Zn0.5Fe2O4 composites at low temperature

AbstractExchange‐coupled hard–soft bi‐magnetic ferrites can be used as isolators, microwave absorption materials, filters, hyperthermia materials, and biosensors with improved energy properties. The nanocomposites with the chemical composition SrInxFe12‐xO4/Ni0.5Zn05Fe2O4 (where x varies from 0.00 to 0.04) have the advantages of both materials: spinel and hexaferrite. The combination of Sr‐hexaferrate with spinel ferrite results in proximity effects, reversal of magnetization in two stages, and blocking temperatures that can be tuned in bi‐magnetic hard and soft ferrites. It was found an anomalius kink in the hysteresis loops and two peaks in the switching field distribution at x ≤ 0.02. The exchange interaction on the surfaces of hard and soft nanoparticles explains the behavior of the magnetic characteristics.

Magnetization reversal of ferromagnetic nanosample by circularly polarized radiation pulse under resonance condition

We consider the problem of the magnetization dynamics of a nanosized ferromagnetic sample caused by the spin–orbit interaction of electrons arising in the field of an incident electromagnetic wave. We discuss the case when the frequency of the incident electromagnetic radiation is close to the frequency of the interband transitions. We show that with the use of high-power lasers, this mechanism causes the appearance of a magnetization component perpendicular to the initial magnetization of the sample. This component shows oscillations with a frequency lower than that of incident electromagnetic waves. These dynamics make possible the magnetization reversal of the sample.

Magnetization reversal phenomenon of higher-order lump and mixed interaction structures on periodic background in the (2+1)-dimensional Heisenberg ferromagnet spin equation

This paper mainly researches a useful model that can describe the rapid magnetization reversal process, namely the (2+1)-dimensional Heisenberg ferromagnet spin equation. Based on its Lax pair, we construct the iterative generalized (r,N−r)-fold Darboux transformation (DT), and obtain new position-controllable higher-order lump, periodic wave and rich mixed lump–breather interaction structures on periodic background. In particular, with the increase of N in the iterative generalized (r,N−r)-fold DT, we find that the structure of the lump and periodic wave can flip over with respect to the background. Moreover, we also find a bright lump structure with two peaks and two valleys, which does not flip with the increase of N. We study the magnetization trajectory and magnetization on the Bloch sphere, from which we discover that the magnetization is distributed in an incomplete unit sphere for the flipped case, while the magnetization is distributed in a complete unit sphere for the non-flipped case. These magnetization reversal phenomena are expected to have potential applications in understanding the rapid magnetization reversal process.

Macroscopic phenomenon of exchange coupling and microscopic effect on magnetization reversal in sintered Nd–Fe–B magnets

Permanent magnets of Nd13.5Fe79.18M1.52B5.8 and Nd13.5Fe79.76M0.94B5.8 were prepared, respectively, via strip casting, jet milling and sintering followed by annealing. By adding the non-ferromagnetic elements M (Al, Cu, Ga and Zr) into the magnets, it could not only modify the microstructure, but also regulate the exchange coupling effect in the sintered magnets. From the macroscopic point of view, the recoil loops exhibit spring behavior in Nd13.5Fe79.76M0.94B5.8, indicating that the energy barrier can be overcome by the intergranular exchange coupling. From the microcosmic point of view, the exchange coupling can increase the domain wall size by suppressing the nucleation of reversed domains, and so the activation volume increases with thermal activation. In Nd13.5Fe79.76M0.94B5.8 the exchange coupling effect is stronger, and both the coercivity of 15.0 kOe and the remanence of 14.3 kGs are a little higher than those of Nd13.5Fe79.18M1.52B5.8 magnets in which the content of non-ferromagnetic elements is a little higher and the exchange coupling effect is weaker. Thus, the exchange coupling does not decrease the coercivity due to the exchange coupling suppressing the nucleation of reversed domains, though the microstructure is inhomogeneous in the sintered magnets of Nd13.5Fe79.76M0.94B5.8. Reducing the defect size and decreasing the defect concentration should be a practical way to improve the coercivity in Nd–Fe–B permanent magnets.

The influence of a copper spacer on the magnetic properties of Pd/Co/Cu/Pd multilayers with perpendicular anisotropy

The potential for technological applications of systems presenting perpendicular magnetic anisotropy is undeniable. With the advent of spintronics and the possibility to explore spin textures, such as skyrmions, in devices, it becomes fundamental to understand how to finely tune the magnetic properties of nanometric systems. In multilayered thin films, characteristics such as domain structure, saturation magnetization and perpendicular anisotropy may be tailored by modifying the interfaces. In the present study, the impact of a copper spacer of varying thickness on the magnetic properties of Pd/Co/Cu/Pd multilayers is investigated. The evolution of magnetization curves, domain patterns and magnetization reversal processes in terms of the spacers thickness are analyzed.

Effects of surface acoustic waves on reversal of magnetic domains in patterned films with perpendicular magnetic anisotropy

In this work, the magnetization reversal of patterned Pt/Co/Pt multilayers influenced by surface acoustic waves is investigated. For each patterned cell, the magnetization reversal involves formation of a reversal nucleus followed by rapid motion of a domain wall. The nucleation probability of the reversal nucleus increases with the power of the applied surface acoustic wave, which is explained by the magnetic droplet model, and fitting the experimental results with this model gives important parameters such as the domain-wall energy density and the reduction rate of local perpendicular anisotropy. The fitting results for different patterned cells are consistent with the experimental results, which validates this model for dealing with such issues.

Influence of interlayer exchange coupling on ultrafast laser-induced magnetization reversal in ferromagnetic spin valves

Influence of interlayer exchange coupling on ultrafast laser-induced magnetization reversal in ferromagnetic spin valves

The underlying mechanism of the strain-induced reversible magnetic state transition in MXene nanosheets

MXenes have emerged as one of the most promising members among the two-dimensional (2D) material family owing to their unique physical-chemical properties and outstanding application prospects. Here, we investigated the unique magnetic properties of Ti2C MXenes monolayer by means of the first-principles calculations combining with the Heisenberg spin Hamiltonian approach. A strain-induced reversible magnetic transition for the Ti2C monolayer could be found in our study. When the strain is applied to the Ti2C monolayer, the magnetic configuration of the Ti2C monolayer transforms from the A-type antiferromagnetic (A-AFM) phase to the ferromagnetic (FM) phase with the biaxial tensile strain larger than 6%. Furthermore, the transition from the A-AFM phase to the FM phase was found to be closely related with the change of the Ti and C atomic magnetic moments. The direct magnetic coupling between Ti and C atoms with the increased Ti and C magnetic moments is able to stabilize the structure due to the weakened superexchange interaction between Ti and C atoms under large tensile strain. This is the underlying driving force for the transition from the A-AFM phase to the FM phase. This work provides a promising pathway to better understand the existence of magnetic reversal behavior in the Ti2C MXenes monolayer and opens the door to future magnetic applications of MXenes.

Magnon-Assisted Magnetization Reversal of Ni81Fe19 Nanostripes on Y3Fe5O12 with Different Interfaces.

Magnetic bit writing by short-wave magnons without conversion to the electrical domain is expected to be a game-changer for in-memory computing architectures. Recently, the reversal of nanomagnets by propagating magnons was demonstrated. However, experiments have not yet explored different wavelengths and the nonlinear excitation regime of magnons required for computational tasks. We report on the magnetization reversal of individual 20 nm thick Ni81Fe19 (Py) nanostripes integrated onto 113 nm thick yttrium iron garnet (YIG). We suppress direct interlayer exchange coupling by an intermediate layer, such as Cu and SiO2. By exciting magnons in YIG with wavelengths λ down to 148 nm we observe the reversal of the integrated ferromagnets in a small external field of 14 mT. Magnons with a small wavelength of λ = 195 nm, i.e., twice the width of the Py nanostripes, induced the reversal at a spin-precessional power of only about 1 nW after propagating over 15 μm in YIG. Such small power value has not been reported so far. Considerations based on dynamic dipolar coupling explain the observed wavelength dependence of the magnon-induced reversal efficiency. For an increased power, the stripes reversed in an external field of only about 1 mT. Our findings are important for the practical implementation of nonvolatile storage of broadband magnon signals in YIG by means of bistable nanomagnets without the need of an appreciable global magnetic field.

Investigation of magnetization dynamics in trilayer width-modulated nanowires

We have investigated the magnetization reversal processes and dynamic behavior of trilayered Py(50 nm)/Pd(tPd)/Py(20 nm) nanowires with periodic width modulation as a function of spacer layer thickness tPd in the range from 0 to 10 nm and compared them with single-layer nanowires. The ferromagnetic resonance spectra show more than three modes that result from a non-uniform demagnetizing field in width-modulated nanowires. We observe that the spacer layer thickness influenced the ferromagnetic resonance spectra, which showed different numbers and values of modes and frequencies due to the different magnetization configurations for different spacer layer thicknesses. We also found that the two ferromagnetic layers are exchange-coupled for tPd = 2 nm nanowire arrays, showing the sharp switching of magnetization from the static measurements and sharp frequency jump from 13.6 to 14.7 GHz around −18 mT from the dynamic measurements. However, for tPd = 10 nm, the two layers switch at different fields, indicating a gradual decrease in magnetization as the reversal is mediated through dipolar coupling. The origin of modes is well explained from the spatial mode profiles of top and bottom magnetic layers. The dynamic responses in this spin-valve-type structure are useful for designing microwave-based spintronic devices.

Understanding the coercivity enhancement mechanism of grain boundary diffused Nd-Fe-B magnets by comparing with commercial equivalent coercivity magnets

The grain boundary diffusion (GBD) technology effectively utilizes heavy rare earth (HRE) elements to improve the coercivity of sintered Nd-Fe-B magnet. Significantly, clarifying its coercivity improvement mechanism is essential for further optimizing the process and performance. Through comparative analysis with commercial conventional magnets (CSH) processing equivalent coercivity, this study investigated the specific mechanism by which the GBD method enhances the coercivity of HRE elements in an efficient manner. To achieve the same coercivity (∼21.4 kOe), GBD magnets contained only 0.25 wt% Tb, whereas CSH magnets had 1.17 wt% Dy and 1.18 wt% Tb. The microstructure analysis revealed that the Tb element in the GBD magnet was concentrated in the outer layer of the grain, constituting 17.37 wt% of the total rare earth content. While, in CSH magnets, the HRE element in the main phase grains accounted for only 9.58 wt% of the total rare earth elements, including Dy (3.83 wt%) and Tb (5.75 wt%). The characteristic core-shell structural grains in GBD magnet also endowed it with an uneven magnetic domain structure and a more concentrated “abrupt” magnetization reversal. Based on the characterization results the nucleation positions of the two types of magnets were analyzed by fitting Hci/Ms and Ha/Ms. The results can serve as a guide for enhancing coercivity in grain boundary diffusion sintered Nd-Fe-B magnets, aiding in process and property optimization, and advancing the understanding of nucleation type mechanisms.